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Guitar strings can go bad due to corrosion, age, and dirt:
Corrosion: Steel strings contain iron, which can rust when exposed to oxygen. This process is accelerated by sweat, oil, dirt, and moisture, especially if the guitar isn't stored in a climate-controlled room. Even strings that aren't played can corrode from humidity and oxidation.
Age: Plain strings can develop rough spots, and bronze wound strings can turn a greenish color.
Dirt: Dirty hands from meals or lotion can leave oils on the string
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