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Asked by Tashiruddin Last Modified
Answer Coordination isomerism occurs when both cation and anion in a complex ion are exchanged with each other. Here's an example:
Consider the coordination compounds [Co(NH₃)₅Cl]Cl₂ and [CoCl₅(NH₃)]²⁻.
In the first compound, [Co(NH₃)₅Cl]Cl₂, the cobalt ion is surrounded by five ammonia ligands and one chloride ion. The counter ion is another chloride ion.
In the second compound, [CoCl₅(NH₃)]²⁻, the cobalt ion is surrounded by five chloride ions and one ammonia ligand. The counter ion is a neutral ammonia molecule.
In both cases, the coordination sphere of cobalt is different, but the overall formula of the compounds remains the same. This is an example of coordination isomerism.
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