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Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds?

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PGT CHEMISTRY 12 year experience teaching XI-XII Students

Apart 3s and 3p orbital 3d orbital of phosphorus also participate in bonding so hybridization of PCl5 is sp3d. Axial bond pairs suffers more repulsion than equitorial bond pairs. Therefore axial bond are longer than equitorial bonds.
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