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The Ha-line of the Balmer series in the emission spectrum of the hydrogen atom is obtained when an electron transitions from the n=3n=3 energy level to the n=2n=2 energy level.
In other words, when an electron that is initially in the third energy level (i.e., n=3n=3) of the hydrogen atom transitions to the second energy level (i.e., n=2n=2), it emits a photon of light corresponding to the Ha-line. This emitted photon has a specific wavelength characteristic of the Ha-line in the visible spectrum.
The transition from the n=3n=3 to n=2n=2 energy level is one of the spectral lines observed in the Balmer series of hydrogen, which consists of transitions of electrons to the second energy level (n=2n=2) from higher energy levels. The Ha-line is specifically associated with the transition from the third to the second energy level and corresponds to a visible spectral line with a specific wavelength in the red part of the spectrum.
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