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(i) To calculate the concentration of HS– ion:
Case I (in the absence of HCl):
Let the concentration of HS– be x M.
Case II (in the presence of HCl):
In the presence of 0.1 M of HCl, let be y M.
(ii) To calculate the concentration of:
Case I (in the absence of 0.1 M HCl):
(From first ionization, case I)
Let
Also, (From first ionization, case I)
Case II (in the presence of 0.1 M HCl):
Again, let the concentration of HS– be X' M.
(From first ionization, case II)
(From HCl, case II)
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