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(i)
(ii)
(iii)
(i)
For the given compound, the number of π-electrons is six. But only four π-electrons are present within the ring. Also there is no conjugation of π-electrons within the ring and the compound is not planar in shape. Hence, the given compound is not aromatic in nature.
(ii)
For the given compound, the number of π-electrons is four.
By Huckel’s rule,
4n + 2 = 4
4n = 2
For a compound to be aromatic, the value of n must be an integer (n = 0, 1, 2…), which is not true for the given compound. Hence, it is not aromatic in nature.
(iii)
For the given compound, the number of π-electrons is eight.
By Huckel’s rule,
4n + 2 = 8
4n = 6
For a compound to be aromatic, the value of n must be an integer (n = 0, 1, 2…). Since the value of n is not an integer, the given compound is not aromatic in nature.
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