Arrange the following

(i) CaH₂, BeH₂ and TiH₂ in order of increasing electrical conductance.

(ii) LiH, NaH and CsH in order of increasing ionic character.

(iii) H–H, D–D and F–F in order of increasing bond dissociation enthalpy.

(iv) NaH, MgH₂ and H₂O in order of increasing reducing property.

(i) The electrical conductance of a molecule depends upon its ionic or covalent nature. Ionic compounds conduct, whereas covalent compounds do not.

BeH₂ is a covalent hydride. Hence, it does not conduct. CaH₂ is an ionic hydride, which conducts electricity in the molten state. Titanium hydride, TiH₂ is metallic in nature and conducts electricity at room temperature. Hence, the increasing order of electrical conductance is as follows:

BeH_2 2 2

(ii) The ionic character of a bond is dependent on the electronegativities of the atoms involved. The higher the difference between the electronegativities of atoms, the smaller is the ionic character.

Electronegativity decreases down the group from Lithium to Caesium. Hence, the ionic character of their hydrides will increase (as shown below).

LiH

(iii) Bond dissociation energy depends upon the bond strength of a molecule, which in turn depends upon the attraction and repulsive forces present in a molecule.

The bond pair in D–D bond is more strongly attracted by the nucleus than the bond pair in H–H bond. This is because of the higher nuclear mass of D₂. The stronger the attraction, the greater will be the bond strength and the higher is the bond dissociation enthalpy. Hence, the bond dissociation enthalpy of D–D is higher than H–H.

However, bond dissociation enthalpy is the minimum in the case of F–F. The bond pair experiences strong repulsion from the lone pairs present on each F-centre.

Therefore, the increasing order of bond dissociation enthalpy is as follows:

F–F

(iv) Ionic hydrides are strong reducing agents. NaH can easily donate its electrons. Hence, it is most reducing in nature.

Both, MgH₂ and H₂O are covalent hydrides. H₂O is less reducing than MgH₂ since the bond dissociation energy of H₂O is higher than MgH₂.

Hence, the increasing order of the reducing property is H₂O ₂