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Acidic character of a species is defined on the basis of ease with which it can lose its H–atoms.
The hybridization state of carbon in the given compound is:
As the s–character increases, the electronegativity of carbon increases and the electrons of C–H bond pair lie closer to the carbon atom. As a result, partial positive charge of H–atom increases and H+ ions are set free.
The s–character increases in the order:
sp3sp2sp
Hence, the decreasing order of acidic behaviour is Ethyne > Benzene > Hexane.
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