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Learn Intext Exercise 9.2 with Free Lessons & Tips

Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:

  1. K[Cr(H2O)2(C2O4)2

  2. [Co(en)3]Cl3

  3. [Co(NH3)5(NO2)](NO3)2

  4. [Pt(NH3)(H2O)Cl2]

  1. Both geometrical (cis-, trans-) isomers for  can exist. Also, optical isomers for cis-isomer exist.

Trans-isomer is optically inactive. On the other hand, cis-isomer is optically active.

(ii) Two optical isomers for  exist.

Two optical isomers are possible for this structure.

(iii) 

A pair of optical isomers:

It can also show linkage isomerism.

and

It can also show ionization isomerism.

(iv) Geometrical (cis-trans-) isomers of can exist.

Comments

Give evidence that [Co(NH3 )5Cl]SO4 and [Co(NH3 )5 (SO4 )]Cl are ionisation isomers.

When ionization isomers are dissolved in water, they ionize to give different ions. These ions then react differently with different reagents to give different products.

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