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Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
K[Cr(H2O)2(C2O4)2
[Co(en)3]Cl3
[Co(NH3)5(NO2)](NO3)2
[Pt(NH3)(H2O)Cl2]
Both geometrical (cis-, trans-) isomers for 
can exist. Also, optical isomers for cis-isomer exist.
Trans-isomer is optically inactive. On the other hand, cis-isomer is optically active.
(ii) Two optical isomers for 
exist.
Two optical isomers are possible for this structure.
(iii) 
A pair of optical isomers:
It can also show linkage isomerism.
and
It can also show ionization isomerism.
(iv) Geometrical (cis-, trans-) isomers of 
can exist.
Give evidence that [Co(NH3 )5Cl]SO4 and [Co(NH3 )5 (SO4 )]Cl are ionisation isomers.
When ionization isomers are dissolved in water, they ionize to give different ions. These ions then react differently with different reagents to give different products.
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