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Chemistry, oxidation of ketones

Monika K.

08 May 0 0

Oxidation of ketones is carried by strong oxidizing agent like concentrated HNO3, KmNO4/H2SO4, dil K2Cr 2O7/H2SO4

For eg

CH3COCH2CH3 +Conc. HNO3= CH3COOH + CH3COOH

CH3COCH2CH2CH3 + conc.HNO3 = CH3COOH + CH3CH2COOH.

Breaking of C ---CO bond takes place according to —poppof's rule

Which states that carbonyl group stays together with smaller alkyl group.

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