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Analytical Chemistry Standard Deviation

Nidhi T.
18/10/2017 0 0
Standard Deviation:
  • The standard deviation, s, is a statistical measure of the precision for a series of repeated measurements. The advantage of using s to quote uncertainty in a result is that it has the same units as the experimental data.
  • Under a normal distribution, (± one standard deviation) encompasses 68% of the measurements and (± two standard deviations) encompasses 96% of the measurements. Standard deviation is calculated from:
  • standard deviation
  • Where N is the number of measurements, xi is each individual measurement, and x-bar is the mean of all measurements.
  •  The quantity (xi - x-bar) is called the "residual" or the "deviation from the mean" for each measurement. The quantity (N - 1) is called the "degrees of freedom" for the measurement.
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